Cover Feature: Synthesis and Characterization of a Layered Scandium MOF Containing a Sulfone‐Functionalized V‐Shaped Linker Molecule (Eur. J. Inorg. Chem. 13/2020). Issue 13 (1st April 2020)

• Record Type: Journal Article
• Authors: Rönfeldt, Pia; Reinsch, Helge; Faßheber, Nancy; Terraschke, Huayna; Stock, Norbert
• Is Part Of: European journal of inorganic chemistry. Issue 13(2020)
• Page Start: 1137
• Page End: 1137
• Publication Date: 2020-04-01
• Subjects: Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.202000282
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : The Cover Feature shows a section of the crystal structure of the new MOF named Sc‐CAU‐11 (CAU = Christian‐Albrechts‐University), which crystallizes in a layered structure with intralayer porosity. The viewer is inside the pore and sees a chain of trans corner‐sharing ScO6 polyhedra, which are connected via V‐shaped linker molecules. The linker molecules are surrounded by blue light, which symbolizes the ligand‐based blue photoluminescence of this compound. A sphere in one polyhedron shines in red light, representing the emission of Eu 3+ ions, which can be incorporated by formal substitution of Sc 3+ ions. More information can be found in the Full Paper by H. Terraschke, N. Stock et al.