Exploiting Radioactive Isotopes: from Pollutant Tracking to Solid State Studies Using a Combined Ab Initio and PAC Approach. Issue 19 (24th April 2020)

• Record Type: Journal Article
• Authors: Amorim, Carlos O.; Gonçalves, João N.; Amaral, Vítor S.
• Is Part Of: European journal of inorganic chemistry. Issue 19(2020)
• Page Start: 1822
• Page End: 1833
• Publication Date: 2020-04-24
• Subjects: Perturbed angular corrections spectroscopy -- Density functional calculations -- Radiochemistry -- Isotopes -- Solid‐state physics; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.202000047
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : In this review we present examples of using radioactive isotopes as probes to study functional materials of fundamental and applied interest presenting colossal magnetoresistance, multiferroic effects, and magnetostructural coupling. Most of the works exploit the hyperfine properties, Electric Field Gradient (EFG) and Hyperfine Magnetic Field (HMF), of these probes through Perturbed Angular Correlation (PAC) spectroscopy. The measurements were complemented with density functional theory calculations to model the relevant properties and correlate the EFG with the electric polarization. We also present a methodological and nuclear physics related contribution consisting on the characterization of a new short‐lived isotope adequate for PAC studies. Finally, an ultra‐sensitive method to quantify the uptake of Hg by nano sorbents based on the tracking the radioactive isotopes of mercury is also reviewed. These works showcase the diversity of our research with radioisotopes, at the interface of different science fields, with combination of different methodologies and different motivations such as fundamental materials physics and chemistry or environmental concerns. Abstract : Radioactive isotopes are a powerful tool to study functional materials, through the exploitation of their hyperfine properties. Here is reviewed a versatile approach using the synergy between the experimental and theoretical hyperfine properties obtained by Perturbed Angular Correlations Spectroscopy and Density Functional Theory, respectively. An ultra‐sensitive method to quantify the uptake of Hg using radioactive isotopes is also reviewed.