Molybdenum Carbide‐Embedded Multichannel Hollow Carbon Nanofibers as Bifunctional Catalysts for Water Splitting. Issue 13 (20th May 2020)

• Record Type: Journal Article
• Authors: Ji, Changchun; Yang, Guang; Ilango, P. Robert; Song, Junnan; Yu, Deshuang; Han, Sujun; Zhang, Dongxing; Li, Linlin; Peng, Shengjie
• Is Part Of: Chemistry, an Asian journal. Volume 15:Issue 13(2020)
• Page Start: 1957
• Page End: 1962
• Publication Date: 2020-05-20
• Subjects: Electrospinning -- Multichannel carbon nanofibers -- Mo2C -- Electrocatalysts -- Water splitting; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201901815
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: With the environmental pollution and non‐renewable fossil fuels, it is imperative to develop eco‐friendly, renewable, and highly efficient electrocatalysts for sustainable energy. Herein, a simple electrospinning process used to synthesis Mo2 C‐embedded multichannel hollow carbon nanofibers (Mo2 C‐MCNFs) and followed by the pyrolysis process. As prepared lotus root‐like nanoarchitecture could offer rich porosity and facilitate the electrolyte infiltration, the Mo2 C‐MCNFs delivered favourable catalytic activity for HER and OER. The resultant catalysts exhibit low overpotentials of 114 mV and 320 mV at a current density of 10 mA cm −2 for HER and OER, respectively. Furthermore, using the Mo2 C‐MCNFs catalysts as a bifunctional electrode toward overall water splitting, which only needs a small cell voltage of 1.68 V to afford a current density of 10 mA cm −2 in the home‐made alkaline electrolyzer. This interesting work presents a simple and effective strategy to further fabricating tunable nanostructures for energy‐related applications. Abstract : Efficient water‐splitting performance was achieved on the Mo2 C‐embedded multichannel hollow carbon nanofibers (Mo2 C‐MCNFs). The superior electrocatalytic performance can be attributed to the superior contact of the electrolyte with active sites of the Mo2 C‐MCNFs due to the lotus root‐like unique architecture.