Highly Dispersed Cobalt Clusters in Nitrogen‐Doped Porous Carbon Enable Multiple Effects for High‐Performance Li–S Battery. Issue 9 (31st January 2020)

• Record Type: Journal Article
• Authors: Wang, Rui; Yang, Jinlong; Chen, Xin; Zhao, Yan; Zhao, Wenguang; Qian, Guoyu; Li, Shunning; Xiao, Yinguo; Chen, Hao; Ye, Yusheng; Zhou, Guangmin; Pan, Feng
• Is Part Of: Advanced energy materials. Volume 10:Issue 9(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-01-31
• Subjects: cobalt clusters -- density functional theory calculations -- Li–S batteries -- porous carbon -- sulfur host; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201903550
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: The lithium–sulfur (Li–S) battery is considered a promising candidate for the next generation of energy storage system due to its high specific energy density and low cost of raw materials. However, the practical application of Li–S batteries is severely limited by several weaknesses such as the shuttle effect of polysulfides and the insulation of the electrochemical products of sulfur and Li2 S/Li2 S2 . Here, by doping nitrogen and integrating highly dispersed cobalt catalysts, a porous carbon nanocage derived from glucose adsorbed metal–organic framework is developed as the host for a sulfur cathode. This host structure combines the reported positive effects, including high conductivity, high sulfur loading, effective stress release, fast lithium‐ion kinetics, fast interface charge transport, fast redox of Li2 S n, and strong physical/chemical absorption, achieving a long cycle life (86% of capacity retention at 1C within 500 cycles) and high rate performance (600 mAh g −1 at 5C) for a Li–S battery. By combining experiments and density functional theoretical calculations, it is demonstrated that the well‐dispersed cobalt clusters play an important role in greatly improving the diffusion dynamics of lithium, and enhance the absorption and conversion capability of polysulfides in the host structure. Abstract : In this work, highly dispersed cobalt clusters in nitrogen‐doped porous carbon have multiple effects on a sulfur cathode, allowing high conductivity, high sulfur loading, effective stress release, fast lithium‐ion kinetics, fast interface charge transport, fast redox of Li2 S n, and strong absorption, which enables a long cycle life (86% of capacity retention at 1C within 500 cycles) and a high rate performance (600 mAh g −1 at 5C) for a Li–S battery.