Design and Synthesis of Sm, Y, La and Nd‐doped CeO2 with a broom‐like hierarchical structure: a photocatalyst with enhanced oxidation performance. Issue 9 (2nd April 2020)

• Record Type: Journal Article
• Authors: Xu, Bin; Yang, Hui; Zhang, Qitao; Yuan, Saisai; Xie, An; Zhang, Ming; Ohno, Teruhisa
• Is Part Of: ChemCatChem. Volume 12:Issue 9(2020)
• Page Start: 2638
• Page End: 2646
• Publication Date: 2020-04-02
• Subjects: Doped Ceria -- Hierarchical structure -- Oxygen vacancies -- Photooxidation; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201902309
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: CeO2 doped with various rare earth (RE) ions (Sm, Y, La and Nd) having a broom‐like hierarchical structure was successfully prepared by a template‐free hydrothermal method. The photooxidation performance of RE‐doped products was significantly better than that of pure CeO2, and comparative experiments showed that Sm‐doped CeO2 (SC) has superior photooxidation activity, resulting about 3.0‐times and 8.5‐times higher activities of bisphenol A (BPA) degradation and of acetaldehyde (CH3 CHO) decomposition, respectively, than those of pure CeO2 . Due to the incorporation of RE ions, the surface exposed cerium ions are partly substituted by those cations, resulting in a higher concentration of oxygen vacancies (Ov ) in RE‐doped CeO2 . The increased Ov can act as a trapping center for photo‐generated electrons to form a doping transition state between the conduction band (CB) and valence band (VB), which can restrict the recombination rate of electrons and holes effectively and lead to an outstanding enhancement of photooxidation performance. Furthermore, abundant highly reactive hydroxyl radicals ( . OH) and superoxide radicals ( . O2 − ), which are efficient intermediates with vivid oxidation ability, can further enhance the photocatalytic activity of RE‐doped CeO2 . A cost‐effective strategy for designing CeO2 ‐based semiconductor photocatalysts doped with multitudinous RE ions that have enhanced photooxidation performance is presented in this paper. Abstract : Photocatalysis : CeO2 doped with Sm, Y, La and Nd having a broom‐like hierarchical structure was successfully synthesized. The enhanced photocatalytic activity can be attributed to a higher concentration of oxygen vacancies caused by doping. During the process of photocatalytic degradation, abundant highly reactive hydroxyl radicals ( . OH) and superoxide radicals ( . O2 − ) are efficient intermediates with vivid oxidation ability.