Ruthenium‐Catalyzed ortho‐Alkenylation of Aroylgermanes. Issue 19 (2nd April 2020)

• Record Type: Journal Article
• Authors: Wang, Hai; Yuan, Yang; Zhang, Youcan; Franke, Robert; Wu, Xiao‐Feng
• Is Part Of: European journal of organic chemistry. Issue 19(2020)
• Page Start: 2842
• Page End: 2845
• Publication Date: 2020-04-02
• Subjects: Ruthenium -- Alkenylation -- Acylgermane -- Styrene -- C–H bond activation; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.202000062
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract : In this communication, a ruthenium‐catalyzed ortho ‐alkenylation of acylgermanes with electron‐deficient alkenes through direct C–H bond activation has been developed. With acylgermane as the directing group, this method provides a straightforward access to diverse acylgermanes derivatives with good functional group tolerance and site‐selectivity under mild reaction conditions. Abstract : A ruthenium‐catalyzed ortho ‐alkenylation of acylgermanes with electron‐deficient alkenes through direct C–H bond activation has been developed. With acylgermane as the directing group, this method provides a straightforward access to diverse acylgermanes derivatives with good functional group tolerance and site‐selectivity under mild reaction conditions.