2‐Carboxyethylgermanium Sesquioxide as A Promising Anode Material for Li‐Ion Batteries. Issue 12 (26th May 2020)

• Record Type: Journal Article
• Authors: Saverina, Evgeniya A.; Kapaev, Roman R.; Stishenko, Pavel V.; Galushko, Alexey S.; Balycheva, Victoriya A.; Ananikov, Valentine P.; Egorov, Mikhail P.; Jouikov, Viatcheslav V.; Troshin, Pavel A.; Syroeshkin, Mikhail A.
• Is Part Of: ChemSusChem. Volume 13:Issue 12(2020)
• Page Start: 3137
• Page End: 3146
• Publication Date: 2020-05-26
• Subjects: anodes -- batteries -- germanium -- lithium -- sesquioxide; Green chemistry -- Periodicals; Sustainable engineering -- Periodicals; Chemistry -- Periodicals; Chemical engineering -- Periodicals; 660
• DOI: 10.1002/cssc.202000852
• Languages: English
• ISSNs: 1864-5631

Abstract

Abstract: Various forms of germanium and germanium‐containing compounds and materials are actively investigated as energy‐intensive alternatives to graphite as the anode of lithium‐ion batteries. The most accessible form—germanium dioxide—has the structure of a 3D polymer, which accounts for its rapid destruction during cycling, and requires the development of further approaches to the production of nanomaterials and various composites based on it. For the first time, we propose here the strategy of using 2‐carboxyethylgermanium sesquioxide ([O1.5 GeCH2 CH2 CO2 H] n, 2‐CEGS), in lieu of GeO2, as a promising, energy‐intensive, and stable new source system for building lithium‐ion anodes. Due to the presence of the organic substituent, the formed polymer has a 1D or a 2D space organization, which facilitates the reversible penetration of lithium into its structure. 2‐CEGS is common and commercially available, completely safe and non‐toxic, insoluble in organic solvents (which is important for battery use) but soluble in water (which is convenient for manufacturing diverse materials from it). This paper reports the preparation of micro‐ (flower‐shaped agglomerates of ≈1 μm thick plates) and nanoformed (needle‐shaped nanoparticles of ≈500×(50–80) nm) 2‐CEGS using methods commonly available in laboratories and industry such as vacuum and freeze‐drying of aqueous solutions of 2‐CEGS. Lithium half‐cell anodes based on 2‐CEGS show a capacity of ≈400 mAh g −1 for microforms and up to ≈700 mAh g −1 for nanoforms, which is almost two times higher than the maximal theoretical capacity of graphite. These anodes are stable during the cycling at various rates. The results of DFT simulations suggest that Li atoms form the stable Li2 O with the oxygen atoms of 2‐CEGS, and actual charge–discharge cycles involve deoxygenated GeC3 H5 molecules. Thus, C3 chains loosen the anode structure compared to pure Ge, improving its ability to accommodate Li ions. Abstract : Better than graphite : A new approach for using 2‐carboxyethyl germanium sesquioxide (2‐CEGS) as a replacement for GeO2 in anodes for lithium‐ion batteries has been proposed. Compared to GeO2, which has a 3D structure, 2‐CEGS can form 1D and 2D polymers, which facilitates the reversible penetration of lithium molecules into its structure. Lithium half‐cell anodes based on 2‐CEGS show a capacity up to ≈700 mAh g −1, which is much higher than the maximal theoretical capacity of graphite.