Simultaneously Realizing Rapid Electron Transfer and Mass Transport in Jellyfish‐Like Mott–Schottky Nanoreactors for Oxygen Reduction Reaction. (20th February 2020)

• Record Type: Journal Article
• Authors: Sun, Zehui; Wang, Yuankun; Zhang, Libo; Wu, Hu; Jin, Yachao; Li, Yuhan; Shi, Yuchuan; Zhu, Tianxiang; Mao, Heng; Liu, Jiamei; Xiao, Chunhui; Ding, Shujiang
• Is Part Of: Advanced functional materials. Volume 30:Number 15(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-02-20
• Subjects: electron transfer -- mass transport -- Mott–Schottky -- oxygen reduction reaction -- spatial confinement; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201910482
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Fundamental understanding of constructing elevated catalysts to realize fast electron transfer and rapid mass transport in oxygen reduction reaction (ORR) chemistry by interface regulation and structure design is important but still ambiguous. Herein, a novel jellyfish‐like Mott–Schottky‐type electrocatalyst is developed to realize fast electron transfer and decipher the structure–mass transport connection during ORR process. Both spectroscopy techniques and density functional theory calculation demonstrate electrons spontaneously transfer from Fe to N‐doped graphited carbon at the heterojunction interface, thus accelerating electron transfer from electrode to reactant. Dynamic analysis indicates unique structure can significantly improve mass transport of oxygen‐species due to two factors: one is electrolyte streaming effect caused by tentacle‐like carbon nanotubes; the other is effective collision probability in the semi‐closed cavity. Therefore, this Mott–Schottky‐type catalyst delievers superior ORR performance with high onset potential, positive half wave potential, and large current density. It also exhibits low overpotential when serving as an air cathode in Zn–air batteries. This work deepens understanding of the two key factors—electron transfer and mass transport—on determining the kinetic reaction of ORR process and offers a new avenue in constructing efficient Mott–Schottky electrocatalysts. Abstract : A novel jellyfish‐like Mott–Schottky oxygen reduction reaction (ORR) electrocatalyst is developed to facilitate electron transfer and mass transport via interfacial regulation and hierarchical porous structure design. This work proposes a method for constructing catalysts with fast charge transfer and mass transport and shows a promising application for simple, scalable, and economical ORR catalysts production.