Simultaneous and Significant Improvements in Efficiency and Stability of Deep‐Blue Organic Light Emitting Diodes through Friedel‐Crafts Arylmethylation of a Fluorophore. Issue 5 (22nd January 2020)

• Record Type: Journal Article
• Authors: Feng, Quanyou; Tan, Kesheng; Zheng, Xiaojun; Xie, Songlin; Xue, Kai; Bo, Yifan; Zhang, He; Lin, Dongqing; Rao, Junfeng; Xie, Xinmiao; Xie, Linghai; Cao, Hongtao; Zhang, Hongmei; Wei, Ying; Huang, Wei
• Is Part Of: ChemPhotoChem. Volume 4:Issue 5(2020)
• Page Start: 321
• Page End: 326
• Publication Date: 2020-01-22
• Subjects: electroluminescence -- excited states -- fluorescence -- organic light emitting diodes -- thermally activated delayed fluorescence; Photochemistry -- Periodicals; Periodicals; Electronic journals; 541.35
• DOI: 10.1002/cptc.201900268
• Languages: English
• ISSNs: 2367-0932

Abstract

Abstract: The molecular design of purely organic fluorophores for highly efficient and stable deep‐blue organic light‐emitting diodes (OLEDs) is still a challenge. Excellent performances in terms of Commission Internationale de l'Eclairage (CIE) coordinates, external quantum efficiency (EQE), brightness and lifespan, often cannot be achieved simultaneously in one deep‐blue OLED. Herein, a novel carbazole‐based thermally activated delayed fluorescence emitter DPFCz ‐TRZ is designed and synthesized through Friedel‐Crafts arylmethylation of Cz ‐TRZ . Compared with the parent compound Cz ‐TRZ, the OLED based on DPFCz ‐TRZ exhibits significantly improved performances with a maximum EQE of 15.5 % and brightness beyond 16000 cd m −2, while retaining similar deep‐blue emission with a CIE coordinate of (0.15, 0.10), an electroluminescence (EL) maximum of λ =445 nm and full width at half maximum (FWHM) of 65 nm. Additionally, the device also shows a respectable lifetime (LT50, time to 50 % of initial luminance) of 78 h at 500 cd m −2, corresponding to a LT50 of 1304 h at 100 cd m −2 . Impressively, a record high EQE of 5.2 % can be obtained at a very high luminance of 10000 cd m −2 . This work demonstrates the first report of simultaneous achievement over 15 % EQE and 1000 h LT50 (100 cd m −2 ) in deep‐blue purely organic electroluminescence devices with a coordinate of (≤0.15, ≤0.10) and maximum brightness beyond 16000 cd m −2 . Abstract : Deep blue something… A new carbazole‐based thermally amplified delayed fluorescence emitter DPFCz ‐TRZ is synthesized through Friedel‐Crafts arylmethylation of the parent fluorophore Cz ‐TRZ . The deep‐blue OLED employing DPFCz ‐TRZ shows significantly improved performances with CIE coordinates of (0.15, 0.10), high EQE of 15.5 %, high luminance over 16000 cd m −2 and a long LT50 of 78 h at 500 cm −2, corresponding to a LT50 of 1304 h at 100 cd m −2 .