High‐Performance Polymeric Materials through Hydrogen‐Bond Cross‐Linking. Issue 18 (19th June 2019)

• Record Type: Journal Article
• Authors: Song, Pingan; Wang, Hao
• Is Part Of: Advanced materials. Volume 32:Issue 18(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-06-19
• Subjects: biomimetics -- high‐performance -- hydrogen‐bond cross‐linking -- polymers; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201901244
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: It has always been critical to develop high‐performance polymeric materials with exceptional mechanical strength and toughness, thermal stability, and even healable properties for meeting performance requirements in industry. Conventional chemical cross‐linking leads to enhanced mechanical strength and thermostability at the expense of extensibility due to mutually exclusive mechanisms. Such major challenges have recently been addressed by using noncovalent cross‐linking of reversible multiple hydrogen‐bonds (H‐bonds) that widely exist in biological materials, such as silk and muscle. Recent decades have witnessed the development of many tailor‐made high‐performance H‐bond cross‐linked polymeric materials. Here, recent advances in H‐bond cross‐linking strategies are reviewed for creating high‐performance polymeric materials. H‐bond cross‐linking of polymers can be realized via i) self‐association of interchain multiple H‐bonding interactions or specific H‐bond cross‐linking motifs, such as 2‐ureido‐4‐pyrimidone units with self‐complementary quadruple H‐bonds and ii) addition of external cross‐linkers, including small molecules, nanoparticles, and polymer aggregates. The resultant cross‐linked polymers normally exhibit tunable high strength, large extensibility, improved thermostability, and healable capability. Such performance portfolios enable these advanced polymers to find many significant cutting‐edge applications. Major challenges facing existing H‐bond cross‐linking strategies are discussed, and some promising approaches for designing H‐bond cross‐linked polymeric materials in the future are also proposed. Abstract : Hydrogen‐bond cross‐linking has recently emerged as a promising strategy for creating high‐performance polymeric materials via self‐association of multiple hydrogen bonds or the addition of external cross‐linkers. These polymers exhibit a unique combination of high strength, large extensibility, thermostability, and even healable capability. Such a performance portfolio enables these polymeric materials to find many potential applications in the electronics and gas‐separation fields.