Rhodium(III)‐Catalyzed Oxidative C(sp3)−H Alkenylation of 8‐Methylquinolines with Maleimides Under Aerobic Conditions. Issue 12 (17th April 2020)

• Record Type: Journal Article
• Authors: Shan, Baode; Kang, Baotao; Song, Mingyue; Wang, Rui; Chen, Guozhu; Li, Cuncheng; Zhao, Huaiqing
• Is Part Of: Advanced synthesis & catalysis. Volume 362:Issue 12(2020)
• Page Start: 2541
• Page End: 2546
• Publication Date: 2020-04-17
• Subjects: rhodium-catalyzed -- C(sp3)−H alkenylation -- copper acetate -- 2, 2, 6, 6-tetramethylpiperidine-1-oxyl -- oxygen; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.202000283
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: A rhodium(III)‐catalyzed C(sp 3 )−H alkenylation of 8‐methylquinolines with electron‐deficient maleimides has been accomplished with the combination of copper acetate, 2, 2, 6, 6‐tetramethylpiperidine‐1‐oxyl and oxygen as the oxidant. A variety of maleimides react with various 8‐methylquinolines to furnish the corresponding alkenylated products in moderate to good yields. Abstract :