Laser‐induced metastable mixed phase of AuNi nanoparticles: a coherent X‐ray diffraction imaging study. (31st March 2020)

• Record Type: Journal Article
• Authors: Kim, Yoonhee; Kim, Chan; Ahn, Kangwoo; Choi, Jungwon; Lee, Su Yong; Kang, Hyon Chol; Noh, Do Young
• Is Part Of: Journal of synchrotron radiation. Volume 27:Part 3(2020)
• Page Start: 725
• Page End: 729
• Publication Date: 2020-03-31
• Subjects: AuNi nanocrystals -- metastable mixed phase -- CXDI -- laser irradiation; Synchrotron radiation -- Periodicals; Free electron lasers -- Periodicals; 539.73505
• DOI: 10.1107/S1600577520001617
• Languages: English
• ISSNs: 0909-0495

Abstract

Abstract : Coherent diffraction imaging in the forward‐scattering geometry reveals AuNi nano alloy particles in a metastable mixed phase. The AuNi nanoparticles irradiated by nanosecond laser pulses exhibit the mixed phase overcoming the miscibility gap. Abstract : The laser annealing process for AuNi nanoparticles has been visualized using coherent X‐ray diffraction imaging (CXDI). AuNi bimetallic alloy nanoparticles, originally phase separated due to the miscibility gap, transform to metastable mixed alloy particles with rounded surface as they are irradiated by laser pulses. A three‐dimensional CXDI shows that the internal part of the AuNi particles is in the mixed phase with preferred compositions at ∼29 at% of Au and ∼90 at% of Au.