Exploiting Supramolecular Interactions from Polymeric Colloids for Strong Anisotropic Adhesion between Solid Surfaces. Issue 14 (16th February 2020)

• Record Type: Journal Article
• Authors: Tardy, Blaise L.; Richardson, Joseph J.; Greca, Luiz G.; Guo, Junling; Ejima, Hirotaka; Rojas, Orlando J.
• Is Part Of: Advanced materials. Volume 32:Issue 14(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-02-16
• Subjects: adhesion -- cellulose -- colloids -- self‐assembly -- supramolecular interactions; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201906886
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Adhesion occurs by covalent bonding, as in reactive structural adhesives, or through noncovalent interactions, which are nearly ubiquitous in nature. A classic example of the latter is gecko feet, where hierarchical features enhance friction across the contact area. Biomimicry of such structured adhesion is regularly achieved by top‐down lithography, which allows for direction‐dependent detachment. However, bottom‐up approaches remain elusive given the scarcity of building blocks that yield strong, cohesive, self‐assembly across multiple length scales. Herein, an exception is introduced, namely, aqueous dispersions of cellulose nanocrystals (CNCs) that form superstructured, adherent layers between solid surfaces upon confined evaporation‐induced self‐assembly (C‐EISA). The inherently strong CNCs ( E A > 140 GPa) align into rigid, nematically ordered lamellae across multiple length scales as a result of the stresses associated with confined evaporation. This long‐range order produces remarkable anisotropic adhesive strength when comparing in‐plane (≈7 MPa) and out‐of‐plane (≤0.08 MPa) directions. These adhesive attributes, resulting from self‐assembly, substantially outperform previous biomimetic adhesives obtained by top‐down microfabrication (dry adhesives, friction driven), and represent a unique fluid (aqueous)‐based system with significant anisotropy of adhesion. By using C‐EISA, new emergent properties will be closely tied with the nature of colloids and their hierarchical assemblies. Abstract : Strong and highly anisometric polymeric crystals of cellulose (cellulose nanocrystals) are explored as adhesives resulting in emergent microstructures. Their self‐assembly under confinement enables alignment of the nanocrystals within macroscale lamellae. The colloidal structural adhesive, architectured from the nanometer to the centimeter‐scale, presents more than 70 folds in anisotropy of adhesion, when comparing stresses applied in‐plane and out‐of‐plane.