Recent Progress in Advanced Organic Electrode Materials for Sodium‐Ion Batteries: Synthesis, Mechanisms, Challenges and Perspectives. (21st January 2020)

• Record Type: Journal Article
• Authors: Yin, Xiuping; Sarkar, Samrat; Shi, Shanshan; Huang, Qiu‐An; Zhao, Hongbin; Yan, Liuming; Zhao, Yufeng; Zhang, Jiujun
• Is Part Of: Advanced functional materials. Volume 30:Number 11(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-01-21
• Subjects: design strategy -- electrode material -- organic material -- progress -- sodium‐ion battery; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201908445
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Rechargeable sodium‐ion batteries (SIBs) are considered attractive alternatives to lithium‐ion batteries for next‐generation sustainable and large‐scale electrochemical energy storage. Organic sodium‐ion batteries (OSIBs) using environmentally benign organic materials as electrodes, which demonstrate high energy/power density and good structural designability, have recently attracted great attention. Nevertheless, the practical applications and popularization of OSIBs are generally restricted by the intrinsic disadvantages related to organic electrodes, such as their low conductivity, poor stability, and high solubility in electrolytes. Here, the latest research progress with regard to electrode materials of OSIBs, ranging from small molecules to organic polymers, is systematically reviewed, with the main focus on the molecular structure design/modification, the electrochemical behavior, and the corresponding charge‐storage mechanism. Particularly, the challenges faced by OSIBs and the effective design strategies are comprehensively summarized from three aspects: function‐oriented molecular design, micromorphology regulation, and construction of organic–inorganic composites. Finally, the perspectives and opportunities in the research of organic electrode materials are discussed. Abstract : This paper comprehensively reviews the recent progress in the research and development of organic electrode materials for organic sodium‐ion batteries with an emphasis on the material design/synthesis/characterization and electrochemical reaction mechanisms to obtain a fundamental understanding of organic cathode materials and their performance. Several strategies to improve the electrochemical performance are summarized and discussed.