In‐situ Transmission Electron Microscope Techniques for Heterogeneous Catalysis. Issue 7 (5th March 2020)

• Record Type: Journal Article
• Authors: He, Bowen; Zhang, Yixiao; Liu, Xi; Chen, Liwei
• Is Part Of: ChemCatChem. Volume 12:Issue 7(2020)
• Page Start: 1853
• Page End: 1872
• Publication Date: 2020-03-05
• Subjects: In-situ TEM -- Specimen holder -- Heterogeneous catalysis -- Structure-activity relationship -- Physicochemical property; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201902285
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: The physicochemical properties of heterogeneous catalysts in static or inert environments often deviate greatly from the properties under in‐situ or working conditions. To gain an insightful understanding of realistic catalyst properties and the corresponding catalytic mechanisms, it is essential to identify and rationalize changes in catalysts under reaction conditions. In recent years, in‐situ transmission electron microscope (in‐situ TEM) techniques have been increasingly developed, offering a unique approach to visualize the evolution of heterogeneous catalysis with ultra‐high spatial resolution, good energy resolution and reasonable temporal resolution under controllable or even realistic catalytic conditions. In this review, we have summarized recent advances in the in‐situ TEM analysis of heterogeneous catalysis, which suggests the great potential of this technique in this important field. Furthermore, technical challenges and possible solutions are discussed. Abstract : Cooking with gas ! Taking the gas‐solid heterogeneous catalysis as an example, gas mixture can be introduced into the sample region of in‐situ TEM during the imaging process. As a result, the kinetic surface evolution process of a catalyst can be monitored.