Absolute stereochemical determination of 1, 2‐diols via complexation with dinaphthyl borinic acid. Issue 6 (22nd March 2020)
- Record Type:
- Journal Article
- Title:
- Absolute stereochemical determination of 1, 2‐diols via complexation with dinaphthyl borinic acid. Issue 6 (22nd March 2020)
- Main Title:
- Absolute stereochemical determination of 1, 2‐diols via complexation with dinaphthyl borinic acid
- Authors:
- Torabi Kohlbouni, Saeedeh
Sarkar, Aritra
Zhang, Jun
Li, Xiaoyong
Borhan, Babak - Abstract:
- Abstract: Rapid derivatization of chiral 1, 2‐diols with dinaphthyl borinic acid (DBA ) leads to a cyclic boronate, enabling the absolute stereochemical prediction via exciton‐coupled circular dichroic (ECCD) of the naphthyl groups. Aryl‐ and alkyl‐substituted 1, 2‐diols derivatized with DBA yield a predictable ECCD, which is also in agreement with theoretical predictions derived from computationally minimized structures. Abstract :
- Is Part Of:
- Chirality. Volume 32:Issue 6(2020)
- Journal:
- Chirality
- Issue:
- Volume 32:Issue 6(2020)
- Issue Display:
- Volume 32, Issue 6 (2020)
- Year:
- 2020
- Volume:
- 32
- Issue:
- 6
- Issue Sort Value:
- 2020-0032-0006-0000
- Page Start:
- 817
- Page End:
- 823
- Publication Date:
- 2020-03-22
- Subjects:
- chiral sensing -- chirality -- dioxaborolane -- ECCD -- stereochemistry
Chirality -- Periodicals
Pharmaceutical chemistry -- Periodicals
541.22 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1520-636X ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chir.23223 ↗
- Languages:
- English
- ISSNs:
- 0899-0042
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3181.124450
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 13150.xml