Frontispiece: Reverse Arene Sandwich Structures Based upon π‐Hole⋅⋅⋅[MII] (d8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile. Issue 13 (15th March 2019)

• Record Type: Journal Article
• Authors: Rozhkov, Anton V.; Krykova, Mariya A.; Ivanov, Daniil M.; Novikov, Alexander S.; Sinelshchikova, Anna A.; Volostnykh, Marina V.; Konovalov, Mikhail A.; Grigoriev, Mikhail S.; Gorbunova, Yulia G.; Kukushkin, Vadim Yu.
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 13(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-03-15
• Subjects: noncovalent interactions -- palladium -- platinum -- reverse sandwich complexes -- π-hole interactions; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201981361
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : Reverse Sandwich Compounds In their Communication on page 4164 ff., V. Y. Kukushkin et al. show how square‐planar Pt II and Pd II systems give reverse sandwich structures in which the charge distribution at the metal and the arenes is opposite to that of classic sandwich species.