Atomically Dispersed Ruthenium Species Inside Metal–Organic Frameworks: Combining the High Activity of Atomic Sites and the Molecular Sieving Effect of MOFs. Issue 13 (25th February 2019)

• Record Type: Journal Article
• Authors: Ji, Shufang; Chen, Yuanjun; Zhao, Shu; Chen, Wenxing; Shi, Lijun; Wang, Yu; Dong, Juncai; Li, Zhi; Li, Fuwei; Chen, Chen; Peng, Qing; Li, Jun; Wang, Dingsheng; Li, Yadong
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 13(2019)
• Page Start: 4271
• Page End: 4275
• Publication Date: 2019-02-25
• Subjects: cluster compounds -- composites -- heterogeneous catalysis -- metal–organic frameworks -- ruthenium; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201814182
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Incorporating atomically dispersed metal species into functionalized metal–organic frameworks (MOFs) can integrate their respective merits for catalysis. A cage‐controlled encapsulation and reduction strategy is used to fabricate single Ru atoms and triatomic Ru3 clusters anchored on ZIF‐8 (Ru1 @ZIF‐8, Ru3 @ZIF‐8). The highly efficient and selective catalysis for semi‐hydrogenation of alkyne is observed. The excellent activity derives from high atom‐efficiency of atomically dispersed Ru active sites and hydrogen enrichment by the ZIF‐8 shell. Meanwhile, ZIF‐8 shell serves as a novel molecular sieve for olefins to achieve absolute regioselectivity of catalyzing terminal alkynes but not internal alkynes. Moreover, the size‐dependent performance between Ru3 @ZIF‐8 and Ru1 @ZIF‐8 is detected in experiment and understood by quantum‐chemical calculations, demonstrating a new and promising approach to optimize catalysts by controlling the number of atoms. Abstract : Single Ru atoms and triatomic Ru3 clusters confined in functionalized ZIF‐8 as composite catalysts combine the advantages of atomically dispersed Ru species and a microporous MOF structure. This facilitates highly efficient and selective catalysis for the partial hydrogenation of alkynes. Size‐dependent performance between Ru3 @ZIF‐8 and Ru1 @ZIF‐8 catalysts is revealed.