Effects of different factors on photodefluorination of perfluorinated compounds by hydrated electrons in organo-montmorillonite system. (January 2018)

• Record Type: Journal Article
• Authors: Tian, Haoting; Gu, Cheng
• Is Part Of: Chemosphere. Volume 191(2018)
• Page Start: 280
• Page End: 287
• Publication Date: 2018-01
• Subjects: Hydrated electrons -- Perfluorocarboxylic acids -- Organo-montmorillonite -- Photodefluorination -- Indole derivatives -- Laser flash photolysis; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2017.10.074
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Perfluorinated compounds (PFCs) are considered as the most recalcitrant organic contaminants. Our previous research has shown that PFCs can be completely defluorinated in the UV/organoclay/3-indole acetic acid system, however, the factors that could affect the degradation of PFCs, are still not clear. In this study, we further investigated the effect of different indole derivatives and organo-modified montmorillonite on the degradation of perfluooctanoic acid (PFOA). Based on multiple linear regression analysis, our results clearly indicate that hydrated electron yields of indole derivatives, adsorption of PFOA and indole derivatives on organo-montmorillonite contributed independently to the degradation of PFOA. In addition, the results also show that the presence of humic substance (even at 10 mg C L −1 ) would not significantly suppress the degradation process due to the strong adsorption of humic substance on the organo-montmorillonite surface. This study would provide more information to design an efficient and environment-friendly system for degradation of PFCs, and this technique will have great potential for treatment of persistent contaminants under mild reaction conditions. Graphical abstract: Image 1 Highlights: Perfluorinated compounds can be effectively defluorinated under mild conditions. The concentration of hydrated electrons are detected by laser flash photolysis. Effect of different factors on the degradation of PFOA are accurately described.