A pre-synthetic strategy to construct single ion conductive covalent organic frameworks. Issue 18 (5th February 2020)

• Record Type: Journal Article
• Authors: Li, Juan; Zhang, Fu-Qiang; Li, Falian; Wu, Zhenzhen; Ma, Canliang; Xu, Qinchao; Wang, Pengfei; Zhang, Xian-Ming
• Is Part Of: Chemical communications. Volume 56:Issue 18(2020)
• Page Start: 2747
• Page End: 2750
• Publication Date: 2020-02-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc00454e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A pre-synthetic strategy was proposed to prepare single-ion conductive COFs by using 2, 5-diaminobenzene sulfonate salts as the monomers. This strategy is advanced in terms of atom economy and easy to operate in structure detection and preparation. Abstract : A pre-synthetic strategy was developed for the construction of single ion conductive covalent organic frameworks (COFs). A high Li + conductivity of 1.6 × 10 −3 S cm −1 at 273 K was achieved, and single Na + and K + COFs were also obtained by using Na + and K + salts as monomers according to this synthetic method.