Ag18(μ8-S)(p-TBBT)16(PPh3)8: symmetry breaking induced by the core to generate chirality. Issue 18 (5th February 2020)
- Record Type:
- Journal Article
- Title:
- Ag18(μ8-S)(p-TBBT)16(PPh3)8: symmetry breaking induced by the core to generate chirality. Issue 18 (5th February 2020)
- Main Title:
- Ag18(μ8-S)(p-TBBT)16(PPh3)8: symmetry breaking induced by the core to generate chirality
- Authors:
- Tian, Fan
Chen, Rong - Abstract:
- Abstract : A novel chiral Ag18 (μ8 -S)( p -TBBT)16 (PPh3 )8 nanocluster with a meso-shell (Ag10 S16 P8 motif) and a crown-like core (SAg8 motif) is reported. Abstract : A chiral silver–sulfur nanocluster with a μ8 -S inside, Ag18 (μ8 -S)( p -TBBT)16 (PPh3 )8, was successfully synthesized and characterized. This nanocluster is composed of a crown-like Ag8 S core and an Ag10 S16 P8 meso-shell. The presence of the core induces symmetry breaking of the nanocluster from S8 to C 4, and therefore endows the cluster with chirality.
- Is Part Of:
- Chemical communications. Volume 56:Issue 18(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 18(2020)
- Issue Display:
- Volume 56, Issue 18 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 18
- Issue Sort Value:
- 2020-0056-0018-0000
- Page Start:
- 2719
- Page End:
- 2722
- Publication Date:
- 2020-02-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc10045h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 12956.xml