Can aromaticity be a kinetic trap? Example of mechanically interlocked aromatic [2-5]catenanes built from cyclo[18]carbon. Issue 18 (5th February 2020)
- Record Type:
- Journal Article
- Title:
- Can aromaticity be a kinetic trap? Example of mechanically interlocked aromatic [2-5]catenanes built from cyclo[18]carbon. Issue 18 (5th February 2020)
- Main Title:
- Can aromaticity be a kinetic trap? Example of mechanically interlocked aromatic [2-5]catenanes built from cyclo[18]carbon
- Authors:
- Fedik, Nikita
Kulichenko, Maksim
Steglenko, Dmitriy
Boldyrev, Alexander I. - Abstract:
- Abstract : Aromaticity serves as a kinetic trap for mechanically interlocked cyclo[18]carbon rings. Abstract : The unusual stability of cyclo[18]carbon arising from its aromaticity might be used to provide the kinetic trapping needed in the design of interlocked systems. The kinetic barrier separating the interlocked rings and the chemically bonded complex is about 30 kcal mol −1 . In addition, the rings can slide freely, which is a promising property for the design of molecular gears and motors.
- Is Part Of:
- Chemical communications. Volume 56:Issue 18(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 18(2020)
- Issue Display:
- Volume 56, Issue 18 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 18
- Issue Sort Value:
- 2020-0056-0018-0000
- Page Start:
- 2711
- Page End:
- 2714
- Publication Date:
- 2020-02-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc09483k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 12956.xml