Transition metal- and solvent-free double hydroboration of nitriles. Issue 4 (31st January 2020)
- Record Type:
- Journal Article
- Title:
- Transition metal- and solvent-free double hydroboration of nitriles. Issue 4 (31st January 2020)
- Main Title:
- Transition metal- and solvent-free double hydroboration of nitriles
- Authors:
- Bedi, Deepika
Brar, Aneelman
Findlater, Michael - Abstract:
- Abstract : An operationally convenient, room temperature synthesis of N, N -diborylated amines via hydroboration of nitriles using a commercially available catalyst. Abstract : A highly efficient, room temperature double hydroboration of nitriles under transition metal-free and solvent-free conditions is reported. Sodium triethylborohydride is used as a catalyst and yields up to 99% are disclosed. Mechanistic studies reveal the reaction proceeds in a stepwise manner with initial formation of a boryl-imine which undergoes a second hydroboration to afford a diborylated amine product.
- Is Part Of:
- Green chemistry. Volume 22:Issue 4(2020)
- Journal:
- Green chemistry
- Issue:
- Volume 22:Issue 4(2020)
- Issue Display:
- Volume 22, Issue 4 (2020)
- Year:
- 2020
- Volume:
- 22
- Issue:
- 4
- Issue Sort Value:
- 2020-0022-0004-0000
- Page Start:
- 1125
- Page End:
- 1128
- Publication Date:
- 2020-01-31
- Subjects:
- Environmental chemistry -- Industrial applications -- Periodicals
Environmental management -- Periodicals
660 - Journal URLs:
- http://www.rsc.org/ ↗
http://pubs.rsc.org/en/journals/journalissues/gc#issueid=gc016010&type=current&issnprint=1463-9262 ↗ - DOI:
- 10.1039/c9gc04260a ↗
- Languages:
- English
- ISSNs:
- 1463-9262
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 4214.935500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 12915.xml