Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination. Issue 8 (22nd January 2020)

• Record Type: Journal Article
• Authors: Bao, Junhui; Wu, Shanshan; Xu, Xin; Huang, Liping; Zhang, Liwei; Kim, Jehan; Zhou, Xiantai; Chen, Yaju; Ji, Hongbing; Huang, Zhegang
• Is Part Of: Dalton transactions. Volume 49:Issue 8(2020)
• Page Start: 2403
• Page End: 2406
• Publication Date: 2020-01-22
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt04668b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A tubular catalyst showed fast catalytic kinetics for CO2 conversion with a TON of 2300 and a TOF of up to 173 h −1 . Abstract : A tubular MOF with adequate active sites is prepared by the bending of metal-coordinated honeycombed frameworks via titration and shows fast catalytic kinetics with lower catalytic loading for CO2 conversion. The TON is observed to be 2300 and the corresponding TOF of up to 173 h −1 is achieved for the first time.