Hermetic seal for perovskite solar cells: An improved plasma enhanced atomic layer deposition encapsulation. (March 2020)

• Record Type: Journal Article
• Authors: Wang, Haoran; Zhao, Yepin; Wang, Zhenyu; Liu, Yunfei; Zhao, Zipeng; Xu, Guangwei; Han, Tae-Hee; Lee, Jin-Wook; Chen, Chen; Bao, Daqian; Huang, Yu; Duan, Yu; Yang, Yang
• Is Part Of: Nano energy. Volume 69(2020)
• Publication Date: 2020-03
• Subjects: Perovskite solar cell -- Stability -- Thin film encapsulation -- Plasma-enhanced atomic layer deposition -- Molecular layer deposition; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2019.104375
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: Unstable nature against moisture is one of the major issues of metallic halide perovskite solar cell application. Thin-film encapsulation is known as a powerful approach to notably enhance the operational stability of perovskite solar cells in humid environment. However, encapsulation layers with ideal gas barrier performance always require harsh fabrication conditions with high temperature and harmful precursors. For this reason, here we provide a mild encapsulation strategy to maintain the original performance of solar cell devices by utilization of ethylene glycol-induced immediate layer to minimize the damage of plasma-enhanced atomic layer deposition to perovskite solar cells. The organic-inorganic alternating encapsulation structure has exhibited a water vapor transmittance rate of 1.3 × 10 −5 g m −2 ·day −1, which is the lowest value among the reported thin film encapsulation layers of perovskite solar cells. Our perovskite solar cells have survived at 80% relative humidity and 30 °C for over 2000 h while preserving 96% of its initial performance. Graphical abstract: Image 1 Highlights: Plasma enhanced atomic layer deposition was applied to the encapsulation of perovskite solar cells. Methyl-rich alucone is used to avoid plasma damage to perovskite batteries. The lowest water vapor transmission rate in the thin film encapsulation of the perovskite solar cells was obtained. The encapsulated standard MAPbI3 perovskite solar cells maintained 96% of initial efficiency for over 2000 h. The encapsulated devices maintained 95% the initial performance after 300 mins under water.