Effect of novel superabsorbent polymer composites on the fresh and hardened properties of alkali-activated slag. (30th January 2020)

• Record Type: Journal Article
• Authors: Fu, Chuanqing; Ye, Hailong; Lei, Aoke; Yang, Guojun; Wan, Pan
• Is Part Of: Construction & building materials. Volume 232(2020)
• Publication Date: 2020-01-30
• Subjects: Low-carbon cement -- Alkali-activated slag -- Superabsorbent polymer -- Fresh properties -- Drying shrinkage; Building materials -- Periodicals; 624.18
• DOI: 10.1016/j.conbuildmat.2019.117225
• Languages: English
• ISSNs: 0950-0618

Abstract

Highlights: Novel poly(sodium-acrylate acrylamide) superabsorbent polymer composites are synthesized. The impact of SAP composites on the fresh and hardened properties of AAS is evaluated. The micro silica and kaolin clay-reinforced SAP composites show better performance in AAS. Abstract: In this work, the poly(sodium-acrylate acrylamide) superabsorbent polymer (SAP) composites reinforced with micro silica and kaolin clay particles are evaluated as novel additives to control and improve the fresh and hardened properties of alkali-activated slag (AAS). The water swelling and retention capacity of plain and modified SAPs in various solutions pertinent to AAS binder systems (including deionized water, saturated Ca(OH)2, 1.0 M NaOH, 0.5 M Na2 CO3, and 0.5 M Na2 SO4 ) are studied using the gravimetric 'tea bag' and thermogravimetric methods, together with molecular analysis. The results show that the use of micro silica and kaolin clay-reinforced SAP composites slightly alleviates the negative influence of conventional SAP counterparts on the flowability, setting, and early-age compressive strength of AAS pastes. Nevertheless, the addition of SAP composites merely postpones the early-stage drying shrinkage development but tends to increase the long-term deformation of hardened AAS in unsealed conditions, likely due to the reduced bulk stiffness with enlarged porosity.