A self-healing transparent polydimethylsiloxane elastomer based on imine bonds. (15th January 2020)

• Record Type: Journal Article
• Authors: Wang, Peng; Yang, Lei; Dai, Bing; Yang, Zhenhuai; Guo, Shuai; Gao, Gang; Xu, Liangge; Sun, Mingqi; Yao, Kaili; Zhu, Jiaqi
• Is Part Of: European polymer journal. Volume 123(2020)
• Publication Date: 2020-01-15
• Subjects: Self-healing -- Polydimethylsiloxanes -- Elastomers -- Imine bonds; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2019.109382
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical abstract: Highlights: A PDMS elastomer based on imine groups is successfully prepared using Schiff base reaction. The elastomer features an outstanding optical transmittance more than 80% in visible region. The elastomer exhibits good mechanical strength, stretchability, and excellent self-healing properties. The elastomer is recyclable and can be used as adhesives. Abstract: Smart materials with self-healing properties that can heal themselves with restored mechanical performance are highly desired. Herein, a transparent healable PDMS (HPDMS) elastomer based on imine bonds is successfully prepared from amino-modified polydimethylsiloxane (PDMS) and 1, 4-diformylbenzene (DFB) through a simple method. The concentration of DFB has a great effect on the gelation process. The elastomer features an outstanding optical transmittance (more than 80%) over the full visible light region. The results of TGA and DSC indicate that the HPDMS elastomer is highly flexible at room temperature and can be used in a wide temperature range. The presence of imine bonding and the formation of Schiff base linkages is proved by the FT-IR and Raman spectra. The reversible imine bond can promote the contact of the fracture surfaces and result in quick and repeatable self-healing without any external intervention such as heat or light. Furthermore, the elastomer exhibits excellent recyclability and reprocessability. Besides, the adhesion test reveals the potential of the elastomer in application as adhesives. We anticipate that this strategy can be employed to prepare a transparent PDMS elastomer with mechanical strength, stretchable, and excellent self-healing properties.