Analysis of combined static load and low temperature hot corrosion induced cracking in CMSX-4 at 550°C. (February 2020)

• Record Type: Journal Article
• Authors: Brooking, L.; Gray, S.; Dawson, K.; Nicholls, J.R.; Simms, N.J.; Sumner, J.; Tatlock, G.J.
• Is Part Of: Corrosion science. Volume 163(2020)
• Publication Date: 2020-02
• Subjects: Superalloy -- Partitioning -- Stress corrosion cracking -- TEM -- Hot corrosion; Corrosion and anti-corrosives -- Periodicals; 620.11223
• DOI: 10.1016/j.corsci.2019.108293
• Languages: English
• ISSNs: 0010-938X

Abstract

Highlights: Crack propagation occurs due to localised corrosion enhanced de-cohesion. Cracks preferentially propagate through the gamma′ precipitates. Corrosion species were found at the crack tip. Tungsten was concentrated in the gamma′ phase contrary to common wisdom. Tensile stress with corrosion are required to generate and propagate crack. Abstract: A CMSX-4 3-point bend specimen was statically loaded under hot corrosion conditions and SEM, (S)TEM and EDX techniques were used to analyse the cracking generated. Sulphur, chlorine, sodium and oxygen were found at the crack tip, and an influence of loading on the corrosion mechanism's preference to interact with either the γ or γʹ was observed. The microscopy analysis is in support of the corrosive mechanism being a combined stress and electrochemical corrosion linked with low temperature hot corrosion, where crack propagation occurs as a result of localised corrosion enhanced material degradation. High magnification EDX mapping identified W as segregating to the γʹ at room temperature.