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An exceptionally long-lived triplet state of red light-absorbing compact phenothiazine-styrylBodipy electron donor/acceptor dyads: a better alternative to the heavy atom-effect?. Issue 11 (16th January 2020)
Record Type:
Journal Article
Title:
An exceptionally long-lived triplet state of red light-absorbing compact phenothiazine-styrylBodipy electron donor/acceptor dyads: a better alternative to the heavy atom-effect?. Issue 11 (16th January 2020)
Main Title:
An exceptionally long-lived triplet state of red light-absorbing compact phenothiazine-styrylBodipy electron donor/acceptor dyads: a better alternative to the heavy atom-effect?
Abstract : Heavy atom-free dyads showing a red light-absorbing and exceptionally long-lived triplet state based on a spin–orbital charge transfer intersystem crossing mechanism. Abstract : A series of phenothiazine-styrylborondipyrromethene compact electron donor/acceptor dyads were prepared to access heavy-atom-free triplet photosensitizers showing red-absorption and especially long-lived triplet states (303 μs), based on the spin orbital charge transfer intersystem crossing (SOCT ISC) mechanism.