Benign Arylations of Dimethyl Itaconate via Heck–Matsuda Reaction Utilizing in‐Situ Generated Palladium on Aluminum Oxide. Issue 1 (3rd January 2020)

• Record Type: Journal Article
• Authors: Matelienė (née Dauksaîtė), Lauryna; Knaup, Jan; von Horsten, Frank; Gu, Xiaoting; Brunner, Heiko
• Is Part Of: European journal of organic chemistry. Issue 1(2020)
• Page Start: 127
• Page End: 135
• Publication Date: 2020-01-03
• Subjects: Arylation -- Arylmethylidene succinates -- Dimethyl itaconate -- Heck‐Matsuda reaction -- Palladium -- Aluminum oxide; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201901708
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract : In situ generated palladium on aluminum oxide provides an active and efficient catalytic system for the preparation of arylmethylidene succinates using the Heck–Matsuda reaction. Beside the monoarylation the first examples of the biarylation of these monomers will be described. Abstract : In situ generated palladium on aluminium oxide provides an active and efficient catalytic system for the preparation of arylmethylidene succinates using the Heck–Matsuda reaction. Beside the monoarylation the first examples of the biarylation of this monomer will be described.