Effect on the characterization of metolachlor polyurea microcapsules with urea instead of polyamines. Issue 1 (1st January 2019)

• Record Type: Journal Article
• Authors: Li, Deming; Wang, Yan; Wang, Jun; Liu, Huanhuan
• Is Part Of: Designed monomers and polymers. Volume 22:Issue 1(2019)
• Page Start: 140
• Page End: 149
• Publication Date: 2019-01-01
• Subjects: Polyurea -- microcapsules -- metolachlor -- interfacial polymerization -- urea -- environmental protection; Monomers -- Periodicals; Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.7005
• DOI: 10.1080/15685551.2019.1653031
• Languages: English
• ISSNs: 1385-772X

Abstract

ABSTRACT: In this paper, a novel metolachlor microcapsules suspension (CS) was prepared by interfacial polymerization. Metolachlor polyurea microcapsules suspension was successfully prepared by urea instead of polyamines which could reduce the use of organic solvents and production costs. The synthesized microcapsules were characterized by Fourier Transform Infrared Spectrometer, Scanning Electron Microscope, Ultraviolet Spectrometry, Thermogravimetric analyses and particle size analyzer. In conclusion, the diameter of the urea microcapsules were the smallest (11.52 μm) and excellent encapsulation efficiency (81.45%). In addition, Urea microcapsules had compact microstructures and global shapes, which had a good thermal stability and metolachlor could be preserved better in the polyurea microcapsules. These results indicated that the prepared microcapsules by urea had better thermal storage properties and physicochemical property. The microcapsule suspension of metolachlor hasn't been researched yet. Therefore, it is significant to prepare microcapsule suspension. More importantly, there is no use of organic solvents in the preparation of microcapsules suspension, which avoided the pollution of solvents to the ecological environment. It is hoped that this polyurea material will be applied in the field of pesticide synthesis and polymers.