Isolation of the novel example of a monomeric organotellurinic acid. Issue 4 (2nd January 2020)

• Record Type: Journal Article
• Authors: Deka, Rajesh; Sarkar, Arup; Butcher, Ray J.; Junk, Peter C.; Turner, David R.; Deacon, Glen B.; Singh, Harkesh B.
• Is Part Of: Dalton transactions. Volume 49:Issue 4(2019)
• Page Start: 1173
• Page End: 1180
• Publication Date: 2020-01-02
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt04013g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The synthesis of the first example of a monomeric, stable organotellurinic acid is reported by utilizing the σ-hole participation of the Te atom with the N atom of the 2-(2′-pyridyl)phenyl moiety. Abstract : The stoichiometrically controlled alkaline hydrolysis of 4, (ppy)TeCl3, [ppy = 2-(2′-pyridyl)phenyl] afforded the partially hydrolyzed μ-oxo-bridged dinuclear telluroxane 5, [(ppyTeCl2 )2 (μ-O)] and a novel example of an Intramolecular Chalcogen Bonding (IChB) stabilized, monomeric organotellurinic acid 6, (ppy)Te(O)OH. The oxidation of diaryl ditelluride 7, (ppyTe)2 using H2 O2 resulted in the isolation of μ-oxo-bridged dimethyl ester 8, [(ppy)Te(O)(OH)(OMe)]2 (O). The molecular structures of 4–6 and 8 are unambiguously authenticated by single crystal X-ray diffraction studies. The electronic structure of monomeric tellurinic acid 6 is investigated using DFT calculations. The Natural Bond Order (NBO) analysis, in corroboration with Atoms in Molecules (AIM) analysis reveals that tellurinic acid 6 is stabilized by σ-hole participation of the tellurium atom with the pyridyl N-atom resulting in strong electrostatic interactions between the N and Te atoms.