Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions. Issue 9 (7th January 2020)
- Record Type:
- Journal Article
- Title:
- Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions. Issue 9 (7th January 2020)
- Main Title:
- Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions
- Authors:
- Shen, Lingyi
Zhao, Yanxia
Dai, Dihua
Yang, Ying-Wei
Wu, Biao
Yang, Xiao-Juan - Abstract:
- Abstract : Grignard reagents with linear alkyl chains are encapsulated and stabilized by pillar[5]arene while preserving their reactivity in Grignard reactions. Abstract : Grignard reagents (RMgX) are widely used in organic synthesis. However, these highly reactive compounds are supplied in inflammable solvents, which causes extra complexity in their transportation. Herein we report that Grignard reagents with linear alkyl chains can be entrapped and stabilized by the macrocyclic host pillar[5]arene while preserving their reactivity.
- Is Part Of:
- Chemical communications. Volume 56:Issue 9(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 9(2020)
- Issue Display:
- Volume 56, Issue 9 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 9
- Issue Sort Value:
- 2020-0056-0009-0000
- Page Start:
- 1381
- Page End:
- 1384
- Publication Date:
- 2020-01-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc08728a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 12664.xml