Imparting Multifunctionality by Utilizing Biporosity in a Zirconium‐Based Metal–Organic Framework. (14th November 2019)

• Record Type: Journal Article
• Authors: Jadhav, Ashwini; Gupta, Kriti; Ninawe, Pranay; Ballav, Nirmalya
• Is Part Of: Angewandte Chemie. Volume 132:Number 6(2020)
• Page Start: 2235
• Page End: 2239
• Publication Date: 2019-11-14
• Subjects: Elektrische Leitfähigkeit -- Leitfähige Polymere -- Metall-organische Gerüste -- Nanokomposite -- Thermische Leitfähigkeit; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201910625
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: In this work, we have synthesized nanocomposites made up of a metal–organic framework (MOF) and conducting polymers by polymerization of specialty monomers such as pyrrole (Py) and 3, 4‐ethylenedioxythiophene (EDOT) in the voids of a stable and biporous Zr‐based MOF (UiO‐66 ). FTIR and Raman data confirmed the presence of polypyrrole (PPy ) and poly3, 4‐ethylenedioxythiophene (PEDOT ) in UiO‐66‐PPy and UiO‐66‐PEDOT nanocomposites, respectively, and PXRD data revealed successful retention of the structure of the MOF. HRTEM images showed successful incorporation of polymer fibers inside the voids of the framework. Owing to the intrinsic biporosity of UiO‐66, polymer chains were observed to selectively occupy only one of the voids. This resulted in a remarkable enhancement (million‐fold) of the electrical conductivity while the nanocomposites retain 60–70 % of the porosity of the original MOF. These semiconducting yet significantly porous MOF nanocomposite systems exhibited ultralow thermal conductivity. Enhanced electrical conductivity with lowered thermal conductivity could qualify such MOF nanocomposites for thermoelectric applications. Abstract : Guter Leiter durch gestopfte Löcher : Der biporöse Charakter von UiO‐66 wird genutzt, um leitfähige Polymergruppen in die Hohlräume des metall‐organischen Gerüsts einzubauen. Die so resultierenden Nanokomposite zeigen eine signifikante Porosität, einhergehend mit einer millionenfachen Erhöhung der elektrischen Leitfähigkeit und einer ultraniedrigen thermischen Leitfähigkeit.