Red‐Carbon‐Quantum‐Dot‐Doped SnO2 Composite with Enhanced Electron Mobility for Efficient and Stable Perovskite Solar Cells. Issue 4 (4th December 2019)

• Record Type: Journal Article
• Authors: Hui, Wei; Yang, Yingguo; Xu, Quan; Gu, Hao; Feng, Shanglei; Su, Zhenhuang; Zhang, Miaoran; Wang, Jiaou; Li, Xiaodong; Fang, Junfeng; Xia, Fei; Xia, Yingdong; Chen, Yonghua; Gao, Xingyu; Huang, Wei
• Is Part Of: Advanced materials. Volume 32:Issue 4(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-12-04
• Subjects: electron transport layers -- planar perovskite solar cells -- red‐carbon quantum dots -- SnO2 -- synchrotron‐based GIXRD; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201906374
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: An efficient electron transport layer (ETL) plays a key role in promoting carrier separation and electron extraction in planar perovskite solar cells (PSCs). An effective composite ETL is fabricated using carboxylic‐acid‐ and hydroxyl‐rich red‐carbon quantum dots (RCQs) to dope low‐temperature solution‐processed SnO2, which dramatically increases its electron mobility by ≈20 times from 9.32 × 10 −4 to 1.73 × 10 −2 cm 2 V −1 s −1 . The mobility achieved is one of the highest reported electron mobilities for modified SnO2 . Fabricated planar PSCs based on this novel SnO2 ETL demonstrate an outstanding improvement in efficiency from 19.15% for PSCs without RCQs up to 22.77% and have enhanced long‐term stability against humidity, preserving over 95% of the initial efficiency after 1000 h under 40–60% humidity at 25 °C. These significant achievements are solely attributed to the excellent electron mobility of the novel ETL, which is also proven to help the passivation of traps/defects at the ETL/perovskite interface and to promote the formation of highly crystallized perovskite, with an enhanced phase purity and uniformity over a large area. These results demonstrate that inexpensive RCQs are simple but excellent additives for producing efficient ETLs in stable high‐performance PSCs as well as other perovskite‐based optoelectronics. Abstract : An effective composite electron transport layer (ETL) is fabricated using carboxylic‐acid‐ and hydroxyl‐rich red‐carbon quantum dots to dope low‐temperature solution‐processed SnO2 . The electron mobility of SnO2 is dramatically increased by ≈20 times from 9.32 × 10 −4 to 1.73 × 10 −2 cm 2 V −1 s −1 . A planar perovskite solar cell based on this novel SnO2 ETL demonstrates an outstanding improvement in efficiency up to 22.77%.