A built-in electric field induced by ferroelectrics increases halogen-free organic solar cell efficiency in various device types. (February 2020)

• Record Type: Journal Article
• Authors: Kumari, Tanya; Jung, Sungwoo; Cho, Yongjoon; Kim, Hwang-Pill; Lee, Jae Won; Oh, Jiyeon; Lee, Jungho; Lee, Sang Myeon; Jeong, Mingyu; Baik, Jeong Min; Jo, Wook; Yang, Changduk
• Is Part Of: Nano energy. Volume 68(2020)
• Publication Date: 2020-02
• Subjects: Electric field -- Grafted copolymers -- Ferroelectric additives -- Organic solar cells -- Environment-friendly processing; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2019.104327
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: In principle, an electric field via ferroelectric materials can affect the photovoltaic properties, although there is not yet a complete mechanistic understanding. Herein, a built-in electric field without a poling processing step was established by introducing developed PVDF-based ferroelectric additives within active-layer matrices of organic solar cells (OSCs). Upon the existence of the ferroelectric polarization induced by the ferroelectric additives in o -xylene/ N -methylpyrrolidone pair featuring halogen-free processing system, high efficiencies of 11.02% and 11.76% are achieved in fullerene and non-fullerene acceptor bulk-heterojunction OSCs, respectively. A comparative study exploring the role of the ferroelectric polarization surrounding the active-layer matrix was also performed using structural, electrical, and morphological techniques, to shed light on the underlying ferroelectric polarization effects on OSCs. Furthermore, the use of the ferroelectric additive is extended to p - n like bilayer OSC to access a rich understanding of the complex enhancement mechanisms afforded by it, demonstrating a highly efficient (11.83%) bilayer device. The above results are fairly comparable to the highest value reported for the recently developed state-of-the-art OSCs processed from halogen-free systems. The use of the ferroelectric additives in the halogen-free system is promising in related organic-semiconductor fields for reasons extending beyond the enhancement of efficiency and the environment-friendly manufacturing. Graphical abstract: Image 1 Highlights: A local built-in electric field induces in the active layer by incorporating ferroelectric additives. The Ferroelectric polarization induced by cosolvent recrystallization without a poling process, resulting in enhanced photovoltaic property is demonstrated. High efficiencies of 11.02% and 11.76% are achieved in fullerene and non-fullerene acceptor test-bed BHJ OSCs, respectively. For the first time, the working mechanisms behind ferroelectric induced electric fields in OSCs are demonstrated. The systematic studies of the ferroelectric effect on the bilayer systems are carried out, resulting in 11.83% efficiency.