Blue‐Pumped Deep Ultraviolet Lasing from Lanthanide‐Doped Lu6O5F8 Upconversion Nanocrystals. Issue 2 (6th November 2019)

• Record Type: Journal Article
• Authors: Du, Yangyang; Wang, Yunfeng; Deng, Zhiqin; Chen, Xian; Yang, Xueqing; Sun, Tianying; Zhang, Xin; Zhu, Guangyu; Yu, Siu Fung; Wang, Feng
• Is Part Of: Advanced optical materials. Volume 8:Issue 2(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-11-06
• Subjects: core–shell -- microcavity lasers -- oxyfluoride -- upconversion nanocrystals -- whispering gallery modes; Optical materials -- Periodicals; Photonics -- Periodicals; 620.11295
• DOI: 10.1002/adom.201900968
• Languages: English
• ISSNs: 2195-1071

Abstract

Abstract: Deep ultraviolet (UV) lasers are essential for enormous use ranging from medical and life science to environmental and industrial applications. Herein, a class of blue‐pumped microcavity lasers operating in the deep UV region is demonstrated by using Lu6 O5 F8 :Pr/Gd@Lu6 O5 F8 upconversion nanocrystals as the gain medium. A hot‐injection synthesis is developed for tuning dimensions of the Lu6 O5 F8 nanocrystals. By synthesizing large‐sized nanocrystals and using inert shell coating, deep ultraviolet emission at 315 nm by blue excitation at 447 nm is realized for the first time in colloidal solutions. Mechanistic investigations suggest that the upconversion stems from sequential absorption of two blue photons by Pr 3+ ions followed by energy transfer to Gd 3+ emitters. By virtue of their small particle size and high dispersibility, the upconversion nanocrystals are readily incorporated into silica resin microcavities with a bottle‐like geometry. Lasing emissions of tunable optical characteristics are achieved from the microcavities through the formation of whispering gallery modes. These findings pave the way for constructing compact lasers operating in the deep UV regime by pumping with sophisticated long‐wavelength lasers. Abstract : Blue‐pumped emission in the deep ultraviolet region is achieved in colloidal Lu6 O5 F8 :Pr/Gd nanocrystals through a two‐photon upconversion process. The upconversion nanocrystals are readily incorporated into silica resin microcavities with a bottle‐like geometry. Lasing emissions of tunable optical characteristics are demonstrated from the microcavities through the formation of whispering gallery modes.