Construction of hierarchical V4C3-MXene/MoS2/C nanohybrids for high rate lithium-ion batteries. Issue 2 (18th December 2019)

• Record Type: Journal Article
• Authors: Bai, Jin; Zhao, Bangchuan; Lin, Shuai; Li, Kunzhen; Zhou, Jiafeng; Dai, Jianming; Zhu, Xuebin; Sun, Yuping
• Is Part Of: Nanoscale. Volume 12:Issue 2(2020)
• Page Start: 1144
• Page End: 1154
• Publication Date: 2019-12-18
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c9nr07646h
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : A novel V4 C3 -MXene/MoS2 /C nanohybrid was synthesized, and it showed an outstanding electrochemical performance when evaluated as an anode for LIBs. Abstract : MoS2 is a promising anode candidate for high-performance lithium-ion batteries (LIBs) due to its unique layered structure and high specific capacity. However, the poor conductivity and unsatisfactory structural stability limit its practical application. Recently, a new class of 2D materials, V4 C3 -Mxene, has been found to combine metallic conductivity, high structural stability and rich surface chemistries. Herein, a facile method has been developed to fabricate V4 C3 -MXene/MoS2 /C nanohybrids. Ultrasmall and few-layered MoS2 nanosheets are uniformly anchored on the surface of V4 C3 -MXene with a thin carbon-coating layer. The ultrasmall and few-layered MoS2 nanosheets can enlarge the specific areas, reduce the diffusion distance of lithium ions, and accelerate the transfer of charge carriers. As a supporting substrate, V4 C3 -MXene endows the nanohybrid with high electrical conductivity, strong structural stability, and fast reaction kinetics. Moreover, the carbon-coating layer can further enhance the electrical conductivity and structural stability of the hybrid material. Benefiting from these advantages, the V4 C3 -MXene/MoS2 /C electrode shows an excellent cycling stability with a high reversible capability of 622.6 mA h g −1 at 1 A g −1 after 450 cycles, and a superior rate capability of 500.0 mA h g −1 at 10 A g −1 . Thus, the V4 C3 -MXene/MoS2 /C nanohybrid could become a promising anode material for high rate LIBs.