A hybrid ionic liquid-based electrolyte for high-performance lithium–sulfur batteries. (9th December 2019)

• Record Type: Journal Article
• Authors: Lu, Hai; Zhu, Yan; Zheng, Bin; Du, Huiling; Zheng, Xuezhao; Liu, Changchun; Yuan, Yan; Fang, Jing; Zhang, Kai
• Is Part Of: New journal of chemistry. Volume 44:Number 2(2020)
• Page Start: 361
• Page End: 368
• Publication Date: 2019-12-09
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c9nj03790j
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : A hybrid IL-based electrolyte consisting of P1, 2O1 TFSI and the support solvent(s) of DOL and/or ETFE was applied in Li–S batteries, and a rational balance between Li2 S x dissolution and Li protection to achieve controllable shuttle was proposed. Abstract : A hybrid ionic liquid (IL)-based electrolyte consisting of N -methoxyethyl- N -methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (P1, 2O1 TFSI) and the support solvent(s) 1, 3-dioxolane (DOL) and/or ethyl 1, 1, 2, 2-tetrafluoroethyl ether (ETFE) was applied in lithium–sulfur batteries. It was found that changing the solvent composition greatly influences the overall properties of the electrolyte. The ternary electrolyte P1, 2O1 TFSI/DOL/ETFE due to the merits of acceptable ion conductivity, moderate polysulfide solubility and good Li compatibility helps the cells to obtain improved cycle stability and rate capability compared to pure IL and the IL/DOL binary system. The synergistic function of two support solvents (DOL and ETFE) with a great difference in donor ability together with IL is considered to establish a reasonable balance between polysulfide dissolution and Li surface protection, thus achieving a controllable shuttle phenomenon and excellent cell performances.