Mass spectrometric detection of enantioselectivity in three-component complexation, copper(ii)-chiral tetradentate ligand-free amino acid in solution. Issue 1 (11th November 2019)

• Record Type: Journal Article
• Authors: Nakakoji, Takashi; Sato, Hirofumi; Ono, Daisuke; Miyake, Hiroyuki; Shinoda, Satoshi; Tsukube, Hiroshi; Kawasaki, Hideya; Arakawa, Ryuichi; Shizuma, Motohiro
• Is Part Of: Chemical communications. Volume 56:Issue 1(2020)
• Page Start: 54
• Page End: 57
• Publication Date: 2019-11-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc07231d
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Enantioselective coordination of a free amino acid as the second ligand of a Cu(ii ) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time by ESI-MS/deuterium-labelled quasienantiomers. Abstract : By using electrospray ionization mass spectrometry coupled with the use of deuterium-labelled quasienantiomers, enantioselective coordination of a free amino acid as the second ligand of a copper(ii ) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time.