Synergic effect of nanostructuring and excess Mn3+ content in the electrochemical performance of Li4Ti5O12–LiNi0.5Mn1.5O4 Li-ion full-cells. Issue 1 (14th January 2020)

• Record Type: Journal Article
• Authors: Haridas, Anulekha K.; Jyothirmayi, Adduru; Sharma, Chandra S.; Rao, Tata N.
• Is Part Of: Journal of materials research. Volume 35:Issue 1(2020)
• Page Start: 42
• Page End: 50
• Publication Date: 2020-01-14
• Subjects: Li, -- nanostructure, -- energy storage; Materials -- Research -- Periodicals; 620.1105
• DOI: 10.1557/jmr.2019.304
• Languages: English
• ISSNs: 0884-2914

Abstract

Abstract: Abstract : The design of high energy Li-ion batteries (LIBs) by coupling high voltage LiNi0.5 Mn1.5 O4 (LNMO) cathode and Li4 Ti5 O12 (LTO) anode ensures effective and safe energy-storage. LTO–LNMO full-cells (FCs) with difference in electrode grain sizes and presence of excess Mn 3+ in cathode were studied using micron-sized commercial LTO, nanostructured LTO donuts (LTOd ), P 43 32 LNMO nanopowders, and nanostructured Fd 3 m LNMO caterpillars (LNMOcplr ). Among the studied FCs, LTOd –LNMOcplr was detected with a stable capacity of 69 mA h/g (1C rate), 99% coulombic efficiency, and 87% capacity retention under 200 cycles of continuous charge–discharge studies. The superior electrochemical performance observed in LTOd –LNMOcplr FC was due to the low charge transfer resistance, which is corroborated to the effect of grain sizes and the longer retention of Mn 3+ in the electrodes. An effective and simple FC design incorporating both nanostructuring and in situ conductivity in electrode materials would aid in developing future high-performance LIBs.