Bifunctional nest-like self-floating microreactor for enhanced photothermal catalysis and biocatalysis. Issue 12 (21st October 2019)

• Record Type: Journal Article
• Authors: Chi, Dechao; Sun, Dandan; Yang, Zekang; Xing, Zipeng; Li, Zhenzi; Zhu, Qi; Zhou, Wei
• Is Part Of: Environmental science. Volume 6:Issue 12(2019)
• Page Start: 3551
• Page End: 3559
• Publication Date: 2019-10-21
• Subjects: Environmental sciences -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c9en00968j
• Languages: English
• ISSNs: 2051-8153

Abstract

Abstract : A bifunctional nest-like self-floating microreactor is fabricated and exhibits excellent photocatalytic and biocatalytic performance, which is ascribed to the synergy of photocatalysis on the outer surface and biocatalysis in the inner surface of the microreactor. Abstract : As a bifunctional nest-like self-floating microreactor, Ag-decorated single crystal black TiO2 nanosheets supported on macroporous polyurethane foam (PUF) with a microbial culture are fabricated via hydrothermal and photodeposition methods combined with an in situ NaBH4 reduction strategy. Photocatalysis and photothermal catalysis reactions occur on the surface; meanwhile, biocatalysis occurs inside the PUF composites. "Bifunctional" refers to a composite that can act as a microreactor that possesses the functions of photocatalysis for degradation of organic contaminants and biocatalysis for microbial degradation. The bifunctional nest-like microreactor floats on the surface of water due to the support of the PUF, which is favorable for using solar light and recycling catalysts. The bifunctional nest-like self-floating microreactor exhibits prominent photocatalytic and biocatalytic performances for the degradation of cephalosporin (96.1%) at low temperature under solar light irradiation that are ∼1.8-fold and 1.2-fold higher than those of single biocatalysis and photocatalysis, respectively. This high activity can be attributed to the synergy of photocatalysis on the outer surface and biocatalysis on the inner surface of the microreactor. After 6 cycles, the activity is nearly constant, indicating that this microreactor is highly stable, which is favourable for practical applications in the field of low-temperature antibiotic wastewater remediation.