A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone. Issue 48 (26th November 2019)

• Record Type: Journal Article
• Authors: Knoll, Daniel M.; Zippel, Christoph; Hassan, Zahid; Nieger, Martin; Weis, Patrick; Kappes, Manfred M.; Bräse, Stefan
• Is Part Of: Dalton transactions. Volume 48:Issue 48(2019)
• Page Start: 17704
• Page End: 17708
• Publication Date: 2019-11-26
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt04366g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A highly stable and distance-defined [2.2]paracyclophane-based Au/Ru heterobimetallic complex shows promising catalytic properties in a visible-light mediated arylative Meyer–Schuster rearrangement. Abstract : We report the synthesis and catalytic application of a highly stable distance-defined Au/Ru heterobimetallic complex. [2.2]Paracyclophane serves as a backbone, holding the two metal centers in a spatial orientation and metal–metal fixed distance. The Au/Ru heterobimetallic complex is highly stable, easily accessible and exhibits promising catalytic activity in a visible-light mediated dual Au/Ru Meyer–Schuster rearrangement.