Noble‐Metal‐Free Colloidal‐Copper Based Low Overpotential Water Oxidation Electrocatalyst. Issue 24 (12th July 2019)

• Record Type: Journal Article
• Authors: Babar, Noor‐Ul‐Ain; Joya, Khurram Saleem; Ehsan, Muhammad Ali; Khan, Majad; Sharif, Muhammad
• Is Part Of: ChemCatChem. Volume 11:Issue 24(2019)
• Page Start: 6022
• Page End: 6030
• Publication Date: 2019-07-12
• Subjects: Catalysis -- electrochemistry -- water splitting -- copper oxide -- low overpotential; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201900202
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: Water oxidation catalysis is gaining more attention in recent times owing to its potential for solar and chemical energy conversion and for green fuel generation. The overwhelming hurdle in this quest is to develop a noble‐metal‐free, efficient, low overpotential water oxidation electrocatalyst exhibiting tremendous stability and to be obtained from earth‐abundant materials. We show here unique copper‐based water oxidation electrocatalyst derived from thin film Cu‐colloidal nanoparticles and is highly efficient, robust for water oxidation. The catalyst advantageously exhibits nanobeads and nanorods type mixed morphological features with narrow size distribution. The onset for oxygen evolution reaction occurs at a small potential of 1.45 VRHE (η=220 mV) which is the lowest observed relative to other copper‐based materials. The catalyst also maintains remarkable stability during long‐term water electrolysis experiments. Moreover, the catalyst shown to exhibit a high electroactive area with a Tafel slope of 52 mV dec 1−, high TOF of 0.81 s 1− and mass activity of 87 mA mg −1 . Copper is an interesting material because it can also serve as CO2 reduction catalysts at the cathode side. The straightforwardly prepared, handy, and inexpensive Cu‐based electrocatalytic system is a flexible catalyst for electrooxidation of water and for chemical energy conversion and is an attractive alternative to Pt, Ir, and Ru based electrocatalysts obtained from expensive resources and tedious methods. Abstract : Rocking the water : Highly efficient, robust copper centered nano‐featured electrocatalytic system derived from Cu‐colloidal NPs is shown to drive kinetically slothful water oxidation reaction at low potential of 1.45 VRHE. A small Tafel slope of just 52 mV dec 1− was obtained from static chronoamperometry technique (CA) represents well stable kinetic of catalyst for OER. Furthermore, the catalyst presented high stability during long term water electrolysis experiment without undergoing any loss in catalytic activity.