New cyanopyridine based conjugated polymers carrying auxiliary electron donors: From molecular design to blue emissive PLEDs. (March 2020)

• Record Type: Journal Article
• Authors: Pilicode, Naveenchandra; Naik, Praveen; Nimith, K.M.; Acharya, Madhukara; Satyanarayan, M.N.; Adhikari, Airody Vasudeva
• Is Part Of: Dyes and pigments. Volume 174(2020)
• Publication Date: 2020-03
• Subjects: Blue light emitter -- Cyanopyridine -- Donor-acceptor -- DFT -- Electroluminescence; Dyes and dyeing -- Periodicals; Pigments -- Periodicals; 667.2
• DOI: 10.1016/j.dyepig.2019.108046
• Languages: English
• ISSNs: 0143-7208

Abstract

Abstract: Three new D-A (Donor-Acceptor) configured conjugated polymers, i.e. PPy 1-3, centered on strong electron accepting cyanopyridine scaffold carrying varied auxiliary donors, viz. phenylene (PPy 1 ), biphenyl (PPy 2 ), and fluorene (PPy 3 ) were designed and synthesized as blue emitters for PLEDs. The new polymers were subjected to spectral, thermal, photophysical and electrochemical characterization. Also, computational studies (DFT) were performed on the repeating units of polymer using Turbomole 7.2 V software package at the B3LYP/TZVP hybrid levels. Further, their weight average molecular masses were found to be 38.8 kDa, 38.9 kDa and 57.7 kDa, respectively as determined by GPC technique. Furthermore, the new polymers PPy 1-3, were shown to be stable thermally up to 308–374 °C. Evidently, they exhibited good photophysical behavior with their optical energy band gaps of 2.53–2.64 eV. Finally, the polymers PPy 1-3 were employed as an active emissive layer in standard ITO/PEDOT:PSS/Polymer/Al configured PLEDs. Interestingly, at 12 V all the newly fabricated devices exhibit a stable blue characteristic electroluminescence with low threshold voltages of 3.40–5.20 V, confirming an efficient injection of electrons in the diodes. From the results, it is clear that, the polymers PPy 1-3, can be considered as prospective blue light emitters for PLED application. Graphical abstract: Three new cyanopyridine based conjugated polymers, PPy1-3 were designed, synthesized and well-characterized as potential blue emissive materials for PLED application. The detailed studies on their thermal, photophysical, electrochemical, theoretical and electroluminescence properties reveal that, the polymers possess all the prerequisites for the device application. Image 1 Highlights: Synthesized three new cyanopyridine based conjugative polymers PPy1-3 for PLED Show light absorption maxima at 365-380 nm and blue emission at 412-442 nm Display optical band gap of 2.53-2.64 eV with florescence quantum yield 39-49%. ·Fabricated ITO/PEDOT:PSS/Polymer/Al configured devices with stable polymers . Electroluminescence maxima appears at 425-452 nm with low threshold voltage.