Rh(III)‐Catalyzed Ring‐Opening Addition of Azabenzonorbornadienes with Cyclic N‐Sulfonyl Ketimines via C−H Bond Activation. Issue 19 (22nd August 2019)

• Record Type: Journal Article
• Authors: Zhang, Xuexin; Gao, Yang; Chen, Jingchao; Fan, Ruifeng; Shi, Guangrui; He, Zhenxiu; Fan, Baomin
• Is Part Of: Advanced synthesis & catalysis. Volume 361:Issue 19(2019)
• Page Start: 4495
• Page End: 4499
• Publication Date: 2019-08-22
• Subjects: Rhodium -- ring-opening addition -- N-sulfonyl ketimine -- azabenzonorbornadiene -- aryldihydronaphthalene; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201900622
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: The rhodium(III)‐catalyzed ring‐opening addition of the cyclic N ‐sulfonyl ketimines with azabenzonorbornadienes via C−H activation was developed. The reactions afforded the corresponding 2‐aryldihydronaphthalenes derivatives in good yield (up to 98%) under redox‐neutral conditions. Abstract :