Highly stereoselective synthesis of aryl/heteroaryl-C-nucleosides via the merger of photoredox and nickel catalysis. Issue 97 (20th November 2019)

• Record Type: Journal Article
• Authors: Ma, Yingying; Liu, Shihui; Xi, Yifan; Li, Hongrui; Yang, Kai; Cheng, Zhihao; Wang, Wei; Zhang, Yongqiang
• Is Part Of: Chemical communications. Volume 55:Issue 97(2019)
• Page Start: 14657
• Page End: 14660
• Publication Date: 2019-11-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc07184a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A photoredox/nickel dual-catalyzed decarboxylative cross-coupling reaction of anomeric ribosyl/deoxyribosyl acids with aryl/heteroaryl bromides has been developed. Abstract : A photoredox/nickel dual-catalyzed decarboxylative cross-coupling reaction of anomeric ribosyl/deoxyribosyl acids with aryl/heteroaryl bromides has been developed. The reaction proceeds smoothly under visible-light irradiation and features the using of cost-effective and easily handled catalysts and starting materials, which allows the highly stereoselective synthesis of diverse aryl/heteroaryl- C -nucleosides in moderate to high yields.