Oil palm empty fruit bunch extract and powder as an eco‐friendly corrosion inhibitor for mild steel: A comparison study. Issue 12 (18th June 2019)

• Record Type: Journal Article
• Authors: Haris, Nur Izzah Nabilah; Sobri, Shafreeza; Yusof, Yus Aniza; Kassim, Norazila
• Is Part Of: Materials and corrosion. Volume 70:Issue 12(2019)
• Page Start: 2326
• Page End: 2333
• Publication Date: 2019-06-18
• Subjects: acid corrosion -- acid solutions -- corrosion inhibitor -- mild steel; Materials -- Periodicals; Metals -- Periodicals; Corrosion and anti-corrosives -- Periodicals; 620.1122305
• DOI: 10.1002/maco.201910959
• Languages: English
• ISSNs: 0947-5117

Abstract

Abstract: A comparison study in terms of inhibition performance between oil palm empty fruit bunch (OPEFB) extract and OPEFB powder against mild steel corrosion in 1 M hydrochloric acid was evaluated using weight loss technique and adsorption isotherms. OPEFB extract and powder were prepared at various concentrations of 0.2%, 0.4%, 0.6%, 0.8%, and 1.0% (v/v) and dosages of 0.2, 0.4, 0.6, 0.8, and 1.0 g, respectively. The results showed that OPEFB extract achieved higher inhibition efficiency (IE) at high concentration and short immersion time compared to OPEFB powder. Despite having lower IE, OPEFB powder seemed to have better behavior; 6.6% IE increment at longer immersion time, gradual release of active compounds and stronger adsorption capacity. Fourier transform infrared (FTIR) and energy‐dispersive X‐ray studies confirmed the presence of active compounds in OPEFB extract and powder that is responsible for inhibition. Thermodynamic study revealed that both OPEFB extract and powder obeyed Langmuir isotherm and worked through physical adsorption. Overall, OPEFB powder is concluded to have better performance as corrosion inhibitor compared with OPEFB extract. Abstract : Morphology of oil palm empty fruit bunch (OPEFB) waste powder was used as a corrosion inhibitor for mild steel acid corrosion. Surprisingly, it has better performances than its extract. This study revealed a simpler way of utilizing agricultural waste without any hassle of extracting and processing the inhibitor, yet giving a comparable inhibitor efficiency, especially for long‐term usage.