Selective detection of trinitrophenol by a Cd(ii)-based coordination compound. Issue 66 (26th November 2019)

• Record Type: Journal Article
• Authors: Dutta, Basudeb; Purkait, Rakesh; Bhunia, Suprava; Khan, Samim; Sinha, Chittaranjan; Mir, Mohammad Hedayetullah
• Is Part Of: RSC advances. Volume 9:Issue 66(2019)
• Page Start: 38718
• Page End: 38723
• Publication Date: 2019-11-26
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c9ra08614e
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A Cd(ii )-based coordination compound, [CdI2 (4-nvp)2 ] (1 ), has been synthesized using CdI2 and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). Abstract : A Cd(ii )-based coordination compound, [CdI2 (4-nvp)2 ] (1 ), has been synthesized using CdI2 and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories.