Experimental and DFT studies of carbon nanotubes covalently functionalized with an imidazole derivative for electrochemical stability and green corrosion inhibition as a barrier layer on the nickel alloy surface in a sulphuric acidic medium. Issue 66 (26th November 2019)

• Record Type: Journal Article
• Authors: N., Palaniappan; Cole, I. S.; Kuznetsov, A. E.; Justin Thomas, K. R.
• Is Part Of: RSC advances. Volume 9:Issue 66(2019)
• Page Start: 38677
• Page End: 38686
• Publication Date: 2019-11-26
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c9ra08123b
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : (A) The electrostatic interaction of a functionalized carbon material with a 111 nickel surface, (B) the OPT structure of 4, 5-DPM + CNT, and (C) 4, 5-DPIM + CNT material chemisorbed on a 111 nickel alloy surface. Abstract : Nickel-based alloys are used for various applications such as in automobiles, superalloys and ship making. Their stability in acidic environments, however, is often not sufficient due to their native oxide films not withstanding harsh conditions. Carbon-based materials, in contrast, have shown high stability in acidic environments. In the present work, 4, 5-diphenyl-imidazole-functionalized carbon nanotubes were investigated as a corrosion-inhibiting barrier layer on nickel alloy surfaces. We studied the corrosion inhibition efficiency of the imidazole-functionalized carbon nanotubes coated on nickel alloys. The materials were characterized using microscopy and spectroscopy methods. DFT studies were performed as well. The corrosion inhibition was evaluated using electrochemical methods. The imidazole-functionalized CNTs were shown to be crystalline and to have tubular structures. They displayed excellent corrosion inhibition on the nickel alloy surface.